Grain boundaries are one of the most important constituents of a polycrystalline material and play a crucial role in dictating the properties of a bulk material in service or under processing conditions. Bulk properties of a material like fatigue strength, corrosion, liquid metal embrittlement, and others strongly depend on grain boundary properties such as cohesive strength, energy, mobility, etc. These boundary properties in turn are governed by the structure and chemistry of a grain boundary. Furthermore, it has recently been realized that grain boundaries themselves can be described as interface-stabilized phases. We are just at the advent to utilize the phase character of grain boundaries as a material design element.
In the first part of this project, we are focusing on the atomic structure and phase transformation in special grain boundaries in aluminum by using dedicated transmission electron microscopy techniques in combination with the atomistic simulations. Epitaxial aluminum thin films are deposited on sapphire substrate by molecular beam epitaxy or other physical vapor deposition techniques to establish a template based methodology for obtaining specific grain boundary types. Electron backscatter diffraction measurements are employed to characterize the global grain boundary structure and types present in the films. Focused ion beam sample preparation allows then to extract specific grain boundaries for further atomic scale investigations of their structure, chemistry and transitions.
The second part of the project is focusing on in-situ TEM experiments to study the phase transformation behavior of the pre-characterized grain boundaries. The main objective is to develop unified correlations of the grain boundary structure, their transitions and properties.
Last, but not least, we will explore the influence of impurity elements on the structure and properties of grain boundaries and how they can be utilized to tailor the phase behavior of these interfaces.
International researcher team presents a novel microstructure design strategy for lean medium-manganese steels with optimized properties in the journal Science
In this project, links are being established between local chemical variation and the mechanical response of laser-processed metallic alloys and advanced materials.
The atomic arrangements in extended planar defects in different types of Laves phases is studied by high-resolution scanning transmission electron microscopy. To understand the role of such defect phases for hydrogen storage, their interaction with hydrogen will be investigated.
The structure of grain boundaries (GBs) is dependent on the crystallographic structure of the material, orientation of the neighbouring grains, composition of material and temperature. The abovementioned conditions set a specific structure of the GB which dictates several properties of the materials, e.g. mechanical behaviour, diffusion, and…
Efficient harvesting of sunlight and (photo-)electrochemical conversion into solar fuels is an emerging energy technology with enormous promise. Such emerging technologies depend critically on materials systems, in which the integration of dissimilar components and the internal interfaces that arise between them determine the functionality.
The aim of this project is to correlate the point defect structure of Fe1-xO to its mechanical, electrical and catalytic properties. Systematic stoichiometric variation of magnetron-sputtered Fe1-xO thin films are investigated regarding structural analysis by transition electron microscopy (TEM) and spectroscopy methods, which can reveal the defect…