Rabe, M.; Toparli, C.; Chen, Y.-H.; Kasian, O.; Mayrhofer, K. J. J.; Erbe, A.: Alkaline manganese electrochemistry studied by in situ and operando spectroscopic methods - metal dissolution, oxide formation and oxygen evolution. Physical Chemistry Chemical Physics 21 (20), pp. 10457 - 10469 (2019)
Toparli, C.; Ebin, B.; Gürmen, S.: Synthesis, structural and magnetic characterization of soft magnetic nanocrystalline ternary FeNiCo particles. Journal of Magnetism and Magnetic Materials 423, pp. 133 - 139 (2017)
Toparli, C.; Sarfraz, A.; Erbe, A.: A new look at oxide formation at the copper/electrolyte interface by in situ spectroscopies. Physical Chemistry Chemical Physics 17, pp. 31670 - 31679 (2015)
Erbe, A.; Nayak, S.; Chen, Y.-H.; Niu, F.; Pander, M.; Tecklenburg, S.; Toparli, C.: How to probe structure, kinetics and dynamics at complex interfaces in situ and operando by optical spectroscopy. In: Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry; part of "Reference Module in Chemistry, Molecular Sciences and Chemical Engineering", pp. 199 - 219 (Ed. Wandelt, K.). Elsevier, Waltham, MA, USA (2017)
Toparli, C.: Passivity and passivity breakdown on copper: In situ and operando observation of surface oxides. Dissertation, Ruhr-Universität Bochum, Fakultät Maschinenbau, Bochum, Germany (2017)
International researcher team presents a novel microstructure design strategy for lean medium-manganese steels with optimized properties in the journal Science
The goal of this project is to optimize the orientation mapping technique using four-dimensional scanning transmission electron microscopy (4D STEM) in conjunction with precession electron diffraction (PED). The development of complementary metal oxide semiconductor (CMOS)-based cameras has revolutionized the capabilities in data acquisition due to…
Grain boundaries (GBs) affect many macroscopic properties of materials. In the case of metals grain growth, Hall–Petch hardening, diffusion, and electrical conductivity, for example, are influenced or caused by GBs. The goal of this project is to investigate the different GB phases (also called complexions) that can occur in tilt boundaries of fcc…
In order to develop more efficient catalysts for energy conversion, the relationship between the surface composition of MXene-based electrode materials and its behavior has to be understood in operando. Our group will demonstrate how APT combined with scanning photoemission electron microscopy can advance the understanding of complex relationships…
This project studies the mechanical properties and microstructural evolution of a transformation-induced plasticity (TRIP)-assisted interstitial high-entropy alloy (iHEA) with a nominal composition of Fe49.5Mn30Co10Cr10C0.5 (at. %) at cryogenic temperature (77 K). We aim to understand the hardening behavior of the iHEA at 77 K, and hence guide the future design of advanced HEA for cryogenic applications.
Statistical significance in materials science is a challenge that has been trying to overcome by miniaturization as in micropillar compression. However, this process is still limited to 4-5 tests per parameter variance, i.e. Size, orientation, grain size, composition, etc. as the process of fabricating pillars and testing has to be done one by one.…