Scientific Events

Host: Prof. Dierk Raabe Location: Max-Planck-Institut für Eisenforschung GmbH

Mathematical and physical simulation of a funnel thin slab continuous casting machine of a Mexican plant

Nanostructure of wet-chemically prepared, polymer-stabilized silver–gold nanoalloys (6 nm) over the entire composition range

Properties of CuCdTeO films: from solid solutions to composites

Properties of CuCdTeO films: from solid solutions to composites

New insights into interfaces of metals, oxides and nanoparticles via APT

New insights into interfaces of metals, oxides and nanoparticles via APT
In many materials, internal interfaces and surfaces are governing their properties. Due to the inherently atomic scale of interfaces, they have notoriously been elusive to structural and chemical analysis, limiting our current understanding about their behavior. Atom probe tomography, as a single atom sensitive mass spectrometry method with atomic resolution achievable, can significantly add to the understanding of interfaces. In this talk, I will present results on the analysis of local chemistry at grain boundaries in metals and oxides and the challenges associated with the data interpretation. This will also include nanomaterials such as nanoparticles and nanowires, where surface distributions of the chemical elements can be investigated and correlated with the particle’s properties. [more]

Adventures at the Atomic Scale: Diffusion and Defect Chemistry using Correlative STEM and Atom Probe Tomography

Developing materials for optical and electrical applications often requires an understanding of the relationships between processing and point defects. Atomic scale relationships such as these are frequently elusive to understand due to a lack of characterization techniques. In this work, I will show examples of nanoscale and atomic scale characterization of oxide and semiconductor point defects determined through atom probe tomography (APT). Specifically, oxygen stoichiometries in oxygen and proton conducting oxides can be directly related to the electrical conductivities where grain boundaries dominate transport. Laser assisted APT also allows for unique opportunities for measuring atomic diffusion where thermal transport can assist transformations from metastable states. Using a “Dynamic” atom probe, atomic scale diffusion can be quantified at the atomic scale in 3-dimensions using a combination of APT and in-situ electron diffraction with a temporal resolution of better than 1 ns. An in-situ STEM / APT instrument engineered and constructed at CSM will be detailed as well as opportunities for using such data for improved APT data reconstruction. [more]

Superplasticity in Ti-6Al-4V: characterisation, modelling and applications

The processing regime relevant to superplasticity in the Ti-6Al-4V alloy is identifed. The effect is found to be potent in the range 850 to 900 deg ?C at strain rates between 0.001/s and 0.0001/s. Within this regime, mechanical behaviour is characterised by steady-state grain size and negligible cavity formation; electron backscatter diffraction studies confirm a random texture, leaving grain boundary sliding as the overarching deformation mechanism. Outside of the superplastic regime, grain size refinement involving recrystallisation and the formation of voids and cavities cause macroscopic softening; low ductility results. Stress hardening is correlated to grain growth and accumulation of dislocations. The findings are used to construct a processing map, on which the dominant deformation mechanisms are identified. Physically-based constitutive equations are presented which are faithful to the observed deformation mechanisms. Internal state variables are used to represent the evolution of grain size, dislocation density and void fraction. Material constants are determined using genetic-algorithm optimisation techniques. Finally, the deformation behaviour of this material in an industrially relevant problem is simulated: the deformation of diffusion-bonded material for the manufacture of hollow, lightweight structures, e.g. those used for fan blades of aeroengines. [more]

Catalysis in action: a few short stories

Catalysis in action: a few short stories
In this talk, I will give an overview of our attempts to design various solid catalysts for industrially important chemical conversions. These reactions include conversion of biomass derived platform chemicals to other value-added chemicals, lower alkane activation and CO2 activation. We try to understand how the structural aspects of catalysts affect the reactivity, which is crucial in developing better catalysts. For this purpose, we try to make use of various characterization techniques. Recent results from our work in this direction will be described, taking a few examples. [more]
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