Reducing Iron Oxides without Carbon by using Hydrogen-Plasma - ROC

Steel is the dominant metallic material. The production per year is 1.8 billion tons, of which 30% can be produced out of recycled melted scrap. The huge rest amount has to be newly produced from oxide minerals reduced by CO in blast furnaces, followed by partial removal of C by O2 in converters. The CO2 emission of these two processes is enormous,  approx. 2.1 tons of CO2 per 1 ton of steel. Steel making thus becomes the largest single greenhouse gas emitter worldwide (~ 8% of all emissions). ROC is intensively involved in basic research needed to drastically cut down these CO2 emissions, by up tp 80% and beyond. This is the biggest single leverage we have to fight global warming.
 

The project ROC is based on two approaches (a) using H instead of C as reductant and (b) using electric arc furnaces operated with a H-containing reducing plasma. This will merge the multiple steps of traditional steel making into a single melting plus reduction process which can run with green electricity, an electric arc furnace operated with a H-containing reducing plasma. ROC’s approach is possible and can be upscaled  by modifying existing furnace technology. The incentive is that solid Fe from other synthesis methods such as direct reduction must anyway be melted after reduction. Hybrid processes, where partially reduced oxides from direct reduction are fed into a reducing plasma, for high energy and H2 efficiency at fast kinetics and high metallization are also addressed. The physical and chemical foundations of these processes, down to atomic scales, are explored using instrumented laboratory furnaces as well as characterization, simulation and machine learning. Specific topics are the elementary nucleation, transport and transformation mechanisms, mixed scrap and ore charging, influence of contaminants from feedstock, plasma parameters, C-free electrodes, slag metallurgy and the role of nanostructure. Project ROC explores how steelmaking can contribute to the drastic reduction of CO2, which is the biggest challenge of our time, by cutting its emissions by 80% and more.

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See although as example

https://www.mpie.de/3007297/research_topics  “ERC project always on top; first place”

https://www.mpie.de/3893203/GB-correlate 

Recent publications

1.
Souza Filho, I. R.; Springer, H.; Ma, Y.; Mahajan, A.; Corrêa da Silva, C.; Kulse, M.; Raabe, D.: Green steel at its crossroads: Hybrid hydrogen-based reduction of iron ores. Journal of Cleaner Production 340, 130805 (2022)

Subprojects

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